Trichlorido{2-dimethoxymethyl-4-methyl-6-[(quinolin-8-yl)iminomethyl]phenolato-κ3 N,N′,O 1}tin(IV)
نویسندگان
چکیده
In the title compound, [Sn(C(20)H(19)N(2)O(3))Cl(3)], the Sn(IV) ion is surrounded by a tridentate monoanionic Schiff base and by three meridional chloride ions in a six-coordinated distorted octa-hedral geometry. The Sn-Cl bond [2.366 (2) Å] trans to nitro-gen is shorter than the others [2.438 (2) and 2.414 (2) Å]. The N-Sn-N angle [76.19 (11)°] is smaller than the O-Sn-N angle [87.89 (10)°] in the Schiff base ligand. No classical inter-molecular hydrogen-bonding inter-actions are observed. The crystal packing exhibits π-π stacking inter-actions, with a distance of 3.595 (2) Å between the centroids of the phenolate ring and the benzene ring of the quinoline group of inversion-related mol-ecules.
منابع مشابه
{4-Bromo-2-[(2-sulfidophenyl)iminomethyl]phenolato-κ3 S,N,O}(triphenylphosphane-κP)nickel(II)
The Ni(II) atom in the title complex, [Ni(C(13)H(8)BrNOS)(C(18)H(15)P)], is coordinated by the N, O and S atoms of the dianionic tridentate ligand, and its square-planar geometry is completed by a phosphane P atom. The dihedral angle between the aromatic rings in the 4-bromo-2-[(2-sulfido-phen-yl)imino-meth-yl]phenolate ligand is 2.01 (14)°. The most prominent feature of the packing is the pres...
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عنوان ژورنال:
دوره 68 شماره
صفحات -
تاریخ انتشار 2012